(via Wahroongai News, Volume 32, Number 4, April 1998)
Chameleon diamonds are rare hydrogen-rich diamonds that change color when exposed to heat. The most famous named chameleon diamond is the 22.28 ct heat-shaped Green Chameleon diamond—a diamond that changes color from grayish green to bright yellow under one of two circumstances.
Heat the green (stable color) chameleon diamond in the flame of an alcohol lamp to a temperature of 200 – 300ºC and its color will convert to an unstable bright yellow. Overheating to ~ 500ºC. If the unstable yellow colored chameleon diamond is in the dark for 24 of more hours, within a few minutes of its removal form the warm darkness its color will revert from unstable bright yellow to stable green color which is caused by the absorption of UV wavelengths from visible light.
The cause of this chameleon effect is an extremely broad absorption extending from ~ 550nm into the infrared, leaving a green window in the visible. Green chameleon diamonds also display characteristic greenish yellow phosphorescence to LWUV, which may last for several minutes after irradiation ceases.
Over recent years at least two other chameleon-type diamonds have been discovered:
-The first group is some pink Argyle diamonds that briefly change to brownish pink when subjected to strong UV irradiation
-The second group is a single specimen that changes from faint pink to colorless after UV irradiation. Gentle heating returns the faint pink color to this diamond. When exposed to UV light this chameleon has a strong apricot pink fluorescence, but a protracted yellowish green phosphorescence to follow.
Monday, March 26, 2007
Riches Of The Earth
By Frank J Anderson
The Rutledge Press
1981 ISBN 0-8317-7739-7
The Rutledge Press writes:
Because of their beauty and usefulness, ornamental, precious, and semi-precious stones have always had a close relationship with human civilization, whether endowed with religious significance, used as building materials, or wrought into works of art.
Riches of the Earth presents a vivid survey of the unique histories of the major precious and semi-precious stones. Beginning with prehistoric man’s first tools and ending with laser beams and holographs, the chapters of Riches of the Earth deal with religion, magic, superstition; associations with famous people and places; legends, discoveries, forgeries, and thefts. Among the wealth of material are the colorful myths surrounding Chinese jade, the story of ornamental stones during the Middle Ages, the magnificence of the world’s most precious royal collections, the symbolism of stones, stories of beautiful treasures lost, and the real powers of stones used today—plus a chapter on the what, where, and how of collecting.
Forty eight pages of full color illustrations enhance this fascinating history of man’s ongoing enchantment with stones. Riches of the Earth is a delight for the connoisseur and a display of excellence to inspire every collector of rocks and minerals.
The Rutledge Press
1981 ISBN 0-8317-7739-7
The Rutledge Press writes:
Because of their beauty and usefulness, ornamental, precious, and semi-precious stones have always had a close relationship with human civilization, whether endowed with religious significance, used as building materials, or wrought into works of art.
Riches of the Earth presents a vivid survey of the unique histories of the major precious and semi-precious stones. Beginning with prehistoric man’s first tools and ending with laser beams and holographs, the chapters of Riches of the Earth deal with religion, magic, superstition; associations with famous people and places; legends, discoveries, forgeries, and thefts. Among the wealth of material are the colorful myths surrounding Chinese jade, the story of ornamental stones during the Middle Ages, the magnificence of the world’s most precious royal collections, the symbolism of stones, stories of beautiful treasures lost, and the real powers of stones used today—plus a chapter on the what, where, and how of collecting.
Forty eight pages of full color illustrations enhance this fascinating history of man’s ongoing enchantment with stones. Riches of the Earth is a delight for the connoisseur and a display of excellence to inspire every collector of rocks and minerals.
Sunday, March 25, 2007
My Fair Lady
Memorable quote (s) from the movie:
Mrs. Higgins (Gladys Cooper): However did you learn good manners with my son around?
Eliza Doolittle (Audrey Hepburn): It was very difficult. I should never have known how ladies and gentlemen really behaved, if it hadn't been for Colonel Pickering. He always showed what he thought and felt about me as if I were something better than a common flower girl. You see, Mrs. Higgins, apart from the things one can pick up, the difference between a lady and a flower girl is not how she behaves, but how she is treated. I shall always be a common flower girl to Professor Higgins, because he always treats me like a common flower girl, and always will. But I know that I shall always be a lady to Colonel Pickering, because he always treats me like a lady, and always will.
Mrs. Higgins (Gladys Cooper): However did you learn good manners with my son around?
Eliza Doolittle (Audrey Hepburn): It was very difficult. I should never have known how ladies and gentlemen really behaved, if it hadn't been for Colonel Pickering. He always showed what he thought and felt about me as if I were something better than a common flower girl. You see, Mrs. Higgins, apart from the things one can pick up, the difference between a lady and a flower girl is not how she behaves, but how she is treated. I shall always be a common flower girl to Professor Higgins, because he always treats me like a common flower girl, and always will. But I know that I shall always be a lady to Colonel Pickering, because he always treats me like a lady, and always will.
A Couple Of Unusual Diamonds
(via Wahroongai News, Volume 32, Number 4, April 1998)
The appearance in the marketplace of parcels of saturated greenish yellow to yellowish green to brownish fancy colored diamonds—with unusual characteristics—has led to suggestions that these colors could have been induced by a new hyperbaric heating treatment that consists of high temperature and pressure heat treatment (? in a Russian Bars apparatus) that reverses naturally occurring aggregation of nitrogen in the diamonds. Suggested source material for this treatment is low quality, mostly Argyle-type natural diamonds.
The treated diamond’s color has two components: a saturated yellow to brownish body color and a strong greenish luminescence to strong visible light emitted by distinctively visible brownish yellow growth lines in the diamond. This gives the green transmitter diamond’s body color a greenish overcast that is readily visible in daylight. When viewed in somewhat subdued lighting these strongly green fluorescent growth lines often contrast strongly against the brownish body color of the diamonds. When exposed to LWUV the growth lines fluoresce a strong green. Examination of the diamond under magnification reveals prominent graining and color zoning paralleling octahedral faces, pitted and corroded (? burnt) facet junctions, girdle, external surfaces of surface-reaching fractures, and heavily bearded girdles.
Examination with gemological hand-held spectroscope revealed pairs of absorption and bright emission lines at 513 and 518nm, absorption lines at 415 (N3 center) and 503nm (H3 center), and a broad absorption band between 465 and 494nm. A more detailed examination with a spectrophotometer confirmed the presence of these features and added a weak absorption peak at 637nm and a weak to strong peak at 985nm (in the invisible near-infrared)—which was assigned to the irradiation high temperature (>1400ºC) annealing induced H2 center.
It is concerning that none of these obviously treated greenish yellow to yellow green to brown diamonds displayed the 595nm, 741nm (GR1) or HIb and HIc absorptions that would be expected to be found in irradiated and heat treated yellow or green diamonds.
The appearance in the marketplace of parcels of saturated greenish yellow to yellowish green to brownish fancy colored diamonds—with unusual characteristics—has led to suggestions that these colors could have been induced by a new hyperbaric heating treatment that consists of high temperature and pressure heat treatment (? in a Russian Bars apparatus) that reverses naturally occurring aggregation of nitrogen in the diamonds. Suggested source material for this treatment is low quality, mostly Argyle-type natural diamonds.
The treated diamond’s color has two components: a saturated yellow to brownish body color and a strong greenish luminescence to strong visible light emitted by distinctively visible brownish yellow growth lines in the diamond. This gives the green transmitter diamond’s body color a greenish overcast that is readily visible in daylight. When viewed in somewhat subdued lighting these strongly green fluorescent growth lines often contrast strongly against the brownish body color of the diamonds. When exposed to LWUV the growth lines fluoresce a strong green. Examination of the diamond under magnification reveals prominent graining and color zoning paralleling octahedral faces, pitted and corroded (? burnt) facet junctions, girdle, external surfaces of surface-reaching fractures, and heavily bearded girdles.
Examination with gemological hand-held spectroscope revealed pairs of absorption and bright emission lines at 513 and 518nm, absorption lines at 415 (N3 center) and 503nm (H3 center), and a broad absorption band between 465 and 494nm. A more detailed examination with a spectrophotometer confirmed the presence of these features and added a weak absorption peak at 637nm and a weak to strong peak at 985nm (in the invisible near-infrared)—which was assigned to the irradiation high temperature (>1400ºC) annealing induced H2 center.
It is concerning that none of these obviously treated greenish yellow to yellow green to brown diamonds displayed the 595nm, 741nm (GR1) or HIb and HIc absorptions that would be expected to be found in irradiated and heat treated yellow or green diamonds.
Sphalerite
(via Wahroongai News, Volume 30, No 12, December, 1996) Grahame Brown writes:
Sphalerite, otherwise known as zinc blende (Zn, Fe, S), is a cubic mineral that commonly occurs as yellow, brown, orange, green, red, and colorless to gray isometric crystals and cleavage fragments. Due to sphalerite’s high refractive index (2.37-2.43), and a very high dispersion (0.156 or x4 diamond), this principal ore of zinc displays a vitreous to adamantine luster on polished surfaces. Its specific gravity varies from 3.9 to 4.1, depending principally on its iron content. Faceted gems, cut from sphalerite, display many diamond-like characteristics. Consequently, this mineral has been used to imitate diamond—in spite of its ready, perfect dodecahedral (6-directions) cleavage.
The source of some of the world’s finest specimen of this mineral have been the lead zinc deposits of the Picos de Europa Mountains in the Cantabria region of northern Spain. The mines of this area, and their minerals, were described and illustrated by de Baranda & Garcia in the May – June 1996 issue of the Mineralogical Record (pp 177-190).
The mines of this area, particularly the Aliva mines, have been sources of gem quality sphalerite from the 1860s until 1990 (when the last mine ceased operations and was permanently sealed). Aliva mine sphalerite, which occurs with smithsonite, hydrozincite, hemimorphite and other sulphides, such as galena, is found in a carbonate (calcite and dolomite) gangue that fills veins and pockets in carbonaceous limestones that form the mountain/s of the region.
Chemical analysis of this sphalerite have revealed that the causes of its attractive red, yellow and green colors are quite complex. While this sphalerite does contain variable amounts of iron, its various colors also contain variable amounts of other rare elements such as germanium, cadmium, and significant amounts of mercury. The interplay of these elemental impurities in creating various colors is interesting. For example, yellow and green varieties contain little germanium, while green varieties contain highest levels of iron, and red varieties contain highest levels of both cadmium and mercury. Obviously there is a need for additional research before precise cause of color of this sphalerite can be established.
Undoubtedly the best paper written on the very gemmy sphalerites from the Aliva mine is a 1992 paper titled Estudio de la esfalerita la mina de Aliva Santander (Espana) by Cristina Sapalski & Fernando Gomez that was published in the June issue of Boletin del Insituto Gemologico Espanol.
Sphalerite, otherwise known as zinc blende (Zn, Fe, S), is a cubic mineral that commonly occurs as yellow, brown, orange, green, red, and colorless to gray isometric crystals and cleavage fragments. Due to sphalerite’s high refractive index (2.37-2.43), and a very high dispersion (0.156 or x4 diamond), this principal ore of zinc displays a vitreous to adamantine luster on polished surfaces. Its specific gravity varies from 3.9 to 4.1, depending principally on its iron content. Faceted gems, cut from sphalerite, display many diamond-like characteristics. Consequently, this mineral has been used to imitate diamond—in spite of its ready, perfect dodecahedral (6-directions) cleavage.
The source of some of the world’s finest specimen of this mineral have been the lead zinc deposits of the Picos de Europa Mountains in the Cantabria region of northern Spain. The mines of this area, and their minerals, were described and illustrated by de Baranda & Garcia in the May – June 1996 issue of the Mineralogical Record (pp 177-190).
The mines of this area, particularly the Aliva mines, have been sources of gem quality sphalerite from the 1860s until 1990 (when the last mine ceased operations and was permanently sealed). Aliva mine sphalerite, which occurs with smithsonite, hydrozincite, hemimorphite and other sulphides, such as galena, is found in a carbonate (calcite and dolomite) gangue that fills veins and pockets in carbonaceous limestones that form the mountain/s of the region.
Chemical analysis of this sphalerite have revealed that the causes of its attractive red, yellow and green colors are quite complex. While this sphalerite does contain variable amounts of iron, its various colors also contain variable amounts of other rare elements such as germanium, cadmium, and significant amounts of mercury. The interplay of these elemental impurities in creating various colors is interesting. For example, yellow and green varieties contain little germanium, while green varieties contain highest levels of iron, and red varieties contain highest levels of both cadmium and mercury. Obviously there is a need for additional research before precise cause of color of this sphalerite can be established.
Undoubtedly the best paper written on the very gemmy sphalerites from the Aliva mine is a 1992 paper titled Estudio de la esfalerita la mina de Aliva Santander (Espana) by Cristina Sapalski & Fernando Gomez that was published in the June issue of Boletin del Insituto Gemologico Espanol.
From The World Of Gemstones
By Prof Dr Hermann Bank
Pinguin – Verlag
1973
Prof Dr Hermann Bank writes:
Gemstones—from antiquity this concept has conjured up the image of something beautiful, something precious, transcending everyday life. Gems are pre-eminently part of the festive occasions of life, of the (now rare) coronations of emperors and kings, of state receptions, evenings at the opera, soirees and family feasts. Set in the appropriate noble metals, they are favored gifts at engagements, weddings, births and similar occasions. Their manifold usage—dynastic, religious, mystic, therapeutic—as well as their employment for adornment and in the industry shows the enormous extent of The World of Gemstones. Apart from the uses of gems it embraces their origin, their recovery, their fashioning and setting, their imitation, testing and evaluation. The present book attempts to answer concisely and intelligibly the manifold questions From The World of Gemstones which have been put by interested laymen, students and budding gemologists during talks, visits to lapidary establishments and lectures. Numerous pictures are intended to complete the information about The World of Gemstones.
About the author
Prof Dr Hermann Bank was the first Chairman of the German Gemmological Society. He taught gemology at the universities of Heidelberg and Mainz, and is the owner of a gem cutting establishment at Idar Oberstein, Germany.
Pinguin – Verlag
1973
Prof Dr Hermann Bank writes:
Gemstones—from antiquity this concept has conjured up the image of something beautiful, something precious, transcending everyday life. Gems are pre-eminently part of the festive occasions of life, of the (now rare) coronations of emperors and kings, of state receptions, evenings at the opera, soirees and family feasts. Set in the appropriate noble metals, they are favored gifts at engagements, weddings, births and similar occasions. Their manifold usage—dynastic, religious, mystic, therapeutic—as well as their employment for adornment and in the industry shows the enormous extent of The World of Gemstones. Apart from the uses of gems it embraces their origin, their recovery, their fashioning and setting, their imitation, testing and evaluation. The present book attempts to answer concisely and intelligibly the manifold questions From The World of Gemstones which have been put by interested laymen, students and budding gemologists during talks, visits to lapidary establishments and lectures. Numerous pictures are intended to complete the information about The World of Gemstones.
About the author
Prof Dr Hermann Bank was the first Chairman of the German Gemmological Society. He taught gemology at the universities of Heidelberg and Mainz, and is the owner of a gem cutting establishment at Idar Oberstein, Germany.
Sideways
Memorable quote (s) from the movie:
Jack (Thomas Haden Church): I might be in love with another woman.
Miles Raymond (Paul Giamatti): In love? Really? 24 hours with some wine-pourer chick and you're fucking in love? Come on! And you're gonna give up everything?
Jack (Thomas Haden Church): Here's what I'm thinking: you and me, we move up here, we buy a vineyard. You design the wine; I'll handle the business side. You get inspired; maybe write another novel, one that can sell.
Miles Raymond (Paul Giamatti): Oh, my God. No, no.
Jack (Thomas Haden Church): As for me, if an audition comes up, LA's right there, man. It's two hours away, not even.........
Miles Raymond (Paul Giamatti): Jesus Christ, you're crazy. You're crazy. You've gone crazy.
Jack (Thomas Haden Church): All I know is that I'm an actor. All I have is my instinct. You're asking me to go against it.
Jack (Thomas Haden Church): I might be in love with another woman.
Miles Raymond (Paul Giamatti): In love? Really? 24 hours with some wine-pourer chick and you're fucking in love? Come on! And you're gonna give up everything?
Jack (Thomas Haden Church): Here's what I'm thinking: you and me, we move up here, we buy a vineyard. You design the wine; I'll handle the business side. You get inspired; maybe write another novel, one that can sell.
Miles Raymond (Paul Giamatti): Oh, my God. No, no.
Jack (Thomas Haden Church): As for me, if an audition comes up, LA's right there, man. It's two hours away, not even.........
Miles Raymond (Paul Giamatti): Jesus Christ, you're crazy. You're crazy. You've gone crazy.
Jack (Thomas Haden Church): All I know is that I'm an actor. All I have is my instinct. You're asking me to go against it.
Natural Colored Blue Quartz
(via Wahroongai News, Volume 30, No.7, July 1996) Grahame Brown writes:
For many years I have made the general statement in lectures on synthetics that ‘blue quartz is never difficult to identify, for blue quartz does not occur naturally’. It would seem that this statement could, and should, be challenged. The reason for this change of opinion is a small paper that was published in the March-April 1996 issue of The Mineralogical Record.
The paper, titled ‘Blue quartz from the Antequera-Olvera Ophite, Malaga, Spain’, describes the occurrence of attractive dipyramidal blue quartz owing its color to aerinite inclusions.
Apparently blue quartz was first reported from the Antequera region of Spain in 1910. This deposit was rediscovered near the Olvera-Pruna road in Cadiz province—a small province that lies just to the east of the British fortress of Gibraltar. Here a clay-lined fractures in an ophitic (rock with a texture dominated by lath-shaped plagioclase crystals completely included within pyroxene) augite diabase = dolerite (a dark colored intrusive rock, containing major labradorite and pyroxene, which characteristically has an ophitic texture) rock host well crystallized dipyramidal (consisting of equally developed positive and negative rhombohedron) blue quartz crystals of 5mm to 1.5cm size.
The blue quartz crystals are actually colorless quartz crystals that are included by fibrous aerinite. These crystals vary in color from deep blue to sky blue. For the interested reader, aerinite is a monoclinic mineral that commonly adopts a fibrous habit.
Other possible causes of blue quartz are……the inclusion of colorless quartz by:
- Submicroscopic inclusions of rutile, producing a blue color in the quartz by Tyndall scattering of white light, and
- Dumortierite, a bluish to purple orthorhombic mineral.
For many years I have made the general statement in lectures on synthetics that ‘blue quartz is never difficult to identify, for blue quartz does not occur naturally’. It would seem that this statement could, and should, be challenged. The reason for this change of opinion is a small paper that was published in the March-April 1996 issue of The Mineralogical Record.
The paper, titled ‘Blue quartz from the Antequera-Olvera Ophite, Malaga, Spain’, describes the occurrence of attractive dipyramidal blue quartz owing its color to aerinite inclusions.
Apparently blue quartz was first reported from the Antequera region of Spain in 1910. This deposit was rediscovered near the Olvera-Pruna road in Cadiz province—a small province that lies just to the east of the British fortress of Gibraltar. Here a clay-lined fractures in an ophitic (rock with a texture dominated by lath-shaped plagioclase crystals completely included within pyroxene) augite diabase = dolerite (a dark colored intrusive rock, containing major labradorite and pyroxene, which characteristically has an ophitic texture) rock host well crystallized dipyramidal (consisting of equally developed positive and negative rhombohedron) blue quartz crystals of 5mm to 1.5cm size.
The blue quartz crystals are actually colorless quartz crystals that are included by fibrous aerinite. These crystals vary in color from deep blue to sky blue. For the interested reader, aerinite is a monoclinic mineral that commonly adopts a fibrous habit.
Other possible causes of blue quartz are……the inclusion of colorless quartz by:
- Submicroscopic inclusions of rutile, producing a blue color in the quartz by Tyndall scattering of white light, and
- Dumortierite, a bluish to purple orthorhombic mineral.
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