Reappearance Of Surface Diffusion Treated Blue Sapphires in Bangkok

(via ICA Lab Alert, No.12, October 21, 1987) AIGS writes:

Discussion
Most gemologists are well aware of the surface diffusion treatment for corundums. A light colored stone is packed in a slurry of coloring agents and heated to near the melting point. This drives the coloring agents just beneath the surface, creating a deeply colored skin. The stone is then lightly repolished.

In the early 1980s many such stones were seen in Bangkok, usually of a blue color, and some stone burners performed the treatment locally. However it seemed that after unscrupulous dealers learned that gemologists could easily spot the treatment, the incentive was gone and such stones largely disappeared from the market. At least they did until this week. Then several stones came to AIGS for testing which had been treated in this way. They differed from those seen in the past in that they were not near colorless stones coated to a deep blue. By skillful repolishing most of the coating was removed, leaving just enough to improve the stone a bit. In other words, the coating made a $100/ct, sapphire into a $150/ct stone. In the past week we have seen over five of these stones. We suspect that one or more local burners may be performing the treatment.

Identification
These stones are much more difficult to identify because most of the surface coating has been removed by careful repolishing, and because the stones do contain a fair amount of naturally occurring color banding inside the stone. Identification may be made, however, by examining the girdle region and facet junctions very carefully under immersion cell. Interestingly enough, horizontal microscopes do not work as well as the Gem Instrument’s ‘Gemolite’ because the light on horizontal microscopes comes from one side only, while in Gemolite the light comes from all directions due to a circular glass diffusing ring. Identifying these diffusion treated stones is made best by careful examination of the stone’s surface under immersion. Color will be found in places to follow the facets, which is impossible in an untreated stone. Again, confusion is easy however, because these stones may contain considerable natural color within the stone. Side-by-side comparison with a known natural stone and a known surface diffusion treated stone will aid in making difficult separations.