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Thursday, April 12, 2007

Crystal-pulled Synthetic Chrysoberyl

(via Gemmology Queensland, Vol.1, No.2, February 2000)

According to Dr Hisashi Machida, of Japan’s Kyocera Corporation, Inamori currently produces twelve (12) synthetics for gem purposes. These man-made materials include flux-grown emerald, flocculated silica based plastic impregnated white and black opal, and synthetic alexandrite, cat’s eye alexandrite, blue sapphire, ruby, star ruby, pink sapphire, yellow sapphire, padparadscha sapphire, and green chrysoberyl which Machida claims are synthesized by a combination of a flux process and pulling.

Japan’s Kyocera Corporation has been producing gem quality Czochralski grown (crystal pulled) synthetic chrysoberyl for many years. While yellow (Fe³+ bearing), colorless, and Cr³+ containing alexandrite chrysoberyls have been available for some years, green and pink chrysoberyl have only recently been added to the product list.

The light green colored synthetic chrysoberyl is virtually inclusion-free, and is colored by V³+ of similar concentration to that found in Tunduru chrysoberyl of comparable color. Detectable quantities of Fe, Ga, and Sn were not found in the Inamori crystal-pulled synthetic chrysoberyl.
A bluish green synthetic chrysoberyl of possible Russian origin, was colored by five times the V³+ found in equivalently colored natural chrysoberyl, about 0.2 wt% Cr2O3. Like the Inamori synthetic, this green synthetic chrysoberyl had no detectable Fe, Ga, Sn.

An experimental pink synthetic chrysoberyl was colored by Ti³+ (the same chromophore that is found in hydrothermally grown pink synthetic beryl. This synthetic also was virtually inclusion free.

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