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Friday, March 23, 2007

Simulants For Paraiba Tourmalines

Today the 4 different types of simulants for Paraiba tourmaline are still encountered in all shapes and sizes.

(via ICA Early Warning Flash, No.47, September 20, 1991) Deutsche Stiftung Edelsteinforschung writes:

Details
In the last weeks some remarkable simulants for blue and greenish blue Paraiba tourmalines have been observed in Idar Oberstein. In lots of cut stones 4 different types of simulants have been found.

- Blue to greenish blue apatite
- Blue irradiated topaz (unheated)
- Beryl-beryl-triplets with a bright blue cement
- Tourmaline glass doublets

Blue and greenish blue apatite has also been found in lots of rough Paraiba tourmalines.

Identification
1. Apatite possesses refractive indices in the same range as tourmaline but the birefringence is distinctly lower. Furthermore, the absorption spectra are quite different; blue and greenish blue apatite shows absorption lines in the red and yellow, which are caused by certain color centers, while Paraiba tourmalines owe their color to copper and manganese, which cause broad absorption bands in the red and green spectral range.

2. Blue irradiated topaz has lower refractive indices than tourmaline and additionally a lower
birefringence, while the density is higher. The artificial coloration by irradiation has been tested by thermoluminescence measurements.

3. The beryl-beryl-triplets are detectable by the lower refractive indices and birefringence compared to tourmaline. The cementing layer can be easily observed by microscopical studies.

4. The tourmaline-glass-doublets can cause more difficulties because the upper part consists of tourmaline. But microscopical observations attest the composite stone. Routine tests revealed doubling of the back facets of tourmaline and single refraction of glass.

Conclusion
Be careful with lots, and investigate each stone of every lot individually even if or especially when the color is similar or nearly the same.

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